(API) Bulk Drugs
MATERIAL SAFETY DATA SHEET OF DIHYDRAZINE SULPHATE
1. Substance / Preparation and company identification

Use : Chemical Intermediate

Dihydrazine sulphate /

Company :
Medinex Laboratories Pvt. Ltd.,
Plot No. 2&3, Survey No.277/1,
Village: Ukhrala-364005.
Taluka: Ghogha, Dist: Bhavnagar.
Gujarat. INDIA.

Emergency Information :

2. Composition / Information on Ingredients

Chemical nature : intermediate

Dihydrazine sulphate :
CAS Number : 13464-80-7
EEC Number :

3. Hazards identification

Toxic if swallowed.
4. First - aid measures

General advice
Immediately remove contaminated clothing. If danger of loss of consciousness, place patient in recovery position and transport accordingly. Apply artificial respiration if necessary. First aid personnel should pay attention to their own safety.

If inhaled :
Keep patient calm, remove to fresh air, seek medical attention.

On skin contact :
Immediately wash thoroughly with soap and water, seek medical attention.

On contact with eyes :
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,consult an eye specialist.

On ingestion :
Rinse mouth immediately and then drink plenty of water, seek medical attention.

5. Fire - fighting measures

Fire :
Not considered to be fire hazard

Explosion :
Not considered to be an explosion hazard.

Suitable extinguishing media :
Water, dry extinguishing media, foam, carbon dioxide.

Special protective equipment :
Wear self-contained breathing apparatus and chemical protective clothing.

Further information :
Collect separately contaminated extinguishing water, do not allow to reach sewage or effluent systems.

6. Accidental release measures

Personal precautions :
Breathing protection required. Avoid contact with the skin, eyes and clothing.

Environmental precautions :
Do not empty into drains.

Methods for cleaning up or taking up :
For small amounts : Pick up with suitable appliance and dispose of.
For large amounts : Pick up with suitable appliance and dispose of.

7. Handling and storage


Handling
Ensure thorough ventilation of stores and work areas.

Protection against fire and explosion :
Prevent electrostatic charge - sources of ignition should be kept well clear- fire extinguishers should be kept handy.

Storage
Further information on storage conditions : Containers should be stored tightly sealed in a dry place. Preferably filled with Nitrogen.

Storage stability : It is stable at above storage condition till its expiry date.

8. Exposure controls and personal protection


Personal Protective equipment

Respiratory protection :
Breathing protection if breathable aerosols / dust are formed.

Hand protection :
Chemical resistant protective gloves (EN 374)

Eye protection .:
Safety glasses with side-shields (frame goggles) EN 166.

9. Physical and chemical properties.


Form : powder.
Colour : White.
Odour : odourless.
Melting point : 85° C
Vapor Pressure : Data not available.
Vapor Density : Data not available.
Boiling Range : Data not available.
Solubility : Insoluble in water.
Molecular Formula : (N2H4)2 . H2SO4.
Molecular Weight : 162.18

10. Stability and reactivity


Hazardous reactions :
There is no Hazardous reactions with air.

11. Toxicological information


LD 50 / LC 50 :
CAS No : 13464-80-7
Oral Rat, LD 50 = 200 mg/kg
Oral, mice, LD 50 =
Carcinogenicity : --
CAS No : 13464-80-7
IARC : --
Epidemiology : No information available.
Teratogenicity : No information available.
Reproductive Effects : No information available.
Neurotoxicity ; No information available.
Mutagenilcity ; No information available.
Other studies ; See actual entry in RTECS for complete information.

12. Ecological information


No information available.

13. Disposal considerations


Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR parts 261.3. additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P - Series : None listed.
RCRA U - Series : None listed.

14. Transport information


ADR :
Class : 6.1
Packing Group : III
Designation of goods : Dihydrazine Sulfate
RID :
Class : 6.1
Packing Group : III
Designation of goods : Dihydrazine Sulfate
Inland waterway transport :
Class : 6.1
Packing Group : III
Designation of goods : Dihydrazine Sulfate
Sea transport :
Class : 6.1
Packing Group : III
Designation of goods : Dihydrazine Sulfate
Air Transport :
Class : 6.1
Packing Group : III
Designation of goods : Dihydrazine Sulfate

15. Regulatory information


Regulations of the European union ( Labelling ) / National legislation / Regulations

Hazard symbol : TN
Risk phrases :
R 45               May cause cancer.
R 23 / 24 / 25  toxic by inhalation, in contact with skin and i swallowed.
R 43               may cause sensitization by skin contact.
R 50 / 53    Very toxic to aquatic organisms may cause long-term adverse effects in                       the aquatic environment.
Safety phrases :
S 53               Avoid exposure-obtain special instructions before use.
S 45               Incase of accident or if you feel unwell, seek medical advice immediately (show                       the label where possible)
S 60               This material and its container must be desposed of a hazardous waste.
S 61              Avoid release to the environment. Refer to special instructions / safety data                      sheets.

CAS No : 13464-80-7

16. Other information

Warranty:
The above information is believed to be corrected but does not purport to be all-inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We shall not be held liable for any damage resulting from handling or from contact with the above product.
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